Bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κO 1}bis(thiocyanato-κN)zinc(II)
نویسندگان
چکیده
The Schiff base 2-[(4-methyl-phen-yl)imino-meth-yl]-6-methoxy-phenol (HL) forms a complex with a Zn(2+) atom and two independent thio-cyanate ions, [Zn(NCS)(2)(C(15)H(15)NO(2))(2)], in which two phenolate O atoms the two independent Schiff base ligands are coordinated to thee Zn(2+) atom. The protonated imine N atoms are involved in an intramolecular hydrogen bond with the phenoxide group. The Zn atom is also coordinated by two N atoms of two thio-cyanate ligands. The coordination environment of the Zn atom is distorted-tetra-hedral.
منابع مشابه
Bis[4-(4-methoxyphenyl)-4H-1,2,4-triazole-κN 1]bis(thiocyanato-κN)zinc(II)
In the title complex, [Zn(NCS)(2)(C(9)H(9)N(3)O)(2)], the Zn(II) ion is coordinated by two N atoms from the NCS(-) anions and two N atoms from two 4-(4-methoxy-phen-yl)-4H-1,2,4-triazole ligands in a slightly distorted tetra-hedral geometry. Three inter-molecular weak hydrogen-bonding contacts of the types C-H⋯N, C-H⋯S and C-H⋯O are observed in the crystal structure.
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متن کاملBis(μ-3,5-dimethyl-4H-1,2,4-triazol-4-amine-κ2 N 1:N 2)bis[bis(thiocyanato-κN)zinc]–bis(3,5-dimethyl-4H-1,2,4-triazol-4-amine-κN 1)bis(thiocyanato-κN)zinc (1/2)
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متن کاملBis{N 2,N 6-bis[(pyridin-3-yl)methyl]pyridine-2,6-dicarboxamide-κN}bis(methanol-κO)bis(thiocyanato-κN)cobalt(II)
In the title compound, [Co(NCS)(2)(C(19)H(17)N(5)O(2))(2)(CH(3)OH)(2)], the Co(II) atom lies on an inversion center and is coordinated by two isothio-cyanate N atoms, two O atoms of methanol mol-ecules and two pyridine N atoms in a slightly distorted octa-hedral environment. Inter-molecular O-H⋯O and N-H⋯N hydrogen bonds join the complex mol-ecules into layers parallel to the bc plane.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008